Press Releases

Fiscal 2005

November 28, 2005
Asahi Kasei Chemicals Corporation

Agreement to license cyclohexanol technology

Asahi Kasei Chemicals Corp. (AKCC) has concluded an agreement to license its cyclohexanol process to Shijiazhuang Coking & Chemical Group Co., Ltd. (SCCG) of China. SCCG will construct a 100,000 ton/year plant using this technology in a chemical industrial park in Shijiazhuang City, Hebei Province, approximately 280 km southwest of Beijing, with start-up scheduled for autumn 2007.

Cyclohexanol is a feedstock for the production of adipic acid, an intermediate for nylon 66 and polyurethane, and of caprolactam, an intermediate for nylon 6. The AKCC cyclohexanol process via cyclohexene, using benzene as initial feedstock, was developed to heighten the competitiveness of AKCC’s nylon 66 operations. The process features outstanding economic efficiency and environmental compatibility with extremely low waste generation. It has been used commercially at the Mizushima Works of AKCC since 1990, and after successive plant expansions capacity now stands at 170,000 tons/year.

SCCG’s business operations are centered on coke and byproducts of coke production, including benzene. It sought to utilize its benzene to produce cyclohexanone to supply to a caprolactam plant planned by Shijiazhuang Chemical Fibre Co., Ltd., a Sinopec Group company. Cyclohexanone is obtained by dehydrogenation of cyclohexanol. The AKCC cyclohexanol process via cyclohexene was selected in recognition of its excellent technological merits and record of performance in commercial operation.



Corporate profiles
Shijiazhuang Coking & Chemical Group Co., Ltd.
Head office:
  No. 23 Tangu St., Shijiazhuang, Hebei, China
Chairman:
  Liu Junli
Main products:
  Coke, benzene, ammonia, hydrogen peroxide, city gas
Paid-in capital:
 

Rmb300 million (at end of 2004)

Sales:
  Rmb1.53 billion (in 2004)
   
Asahi Kasei Chemicals Corp.
Head office:
 

1-1-2 Yurakucho, Chiyoda-ku, Tokyo, Japan

President:
  Taketsugu Fujiwara
Paid-in capital:
  ¥3 billion (as of April 1, 2005)
Sales:
 

¥557.4 billion* (year ended March 31, 2005)

* Consolidated net sales of Chemicals operating segment of Asahi Kasei Corporation.

Reference material
AKCC cyclohexanol process via cyclohexene
 
Process flow:
   Process flow
 
Features:
 
  • Near 100% carbon yield with coproduct cyclohexane for resource efficiency and low waste
  • Hydrogen consumption one third lower than with conventional process
  • Reaction in aqueous phase for inherent process safety
 
Awards received:
 
  • CSJ Award for Technical Achievements from The Chemical Society of Japan, 1992
  • Technology Award from The Catalysis Society of Japan, 1992
  • SCEJ Technology Award from The Society of Chemical Engineers, Japan, 1992
  • Technology Award from The Okochi Memorial Foundation, 1992
 
Cyclohexanol applications
  Cyclohexanol applications
   
Conventional caprolactam production process
 

 Conventional caprolactam production process



back