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Technical Information leather (synthetic leather, artificial leather, etc.)

Use in leather applications Use of DURANOL™ allows you to obtain a polyurethane resin with excellent hydrolysis resistance, moisture heat resistance, chemical resistance, and Abrasion resistance, as well as to improve the durability of polyurethane resins for leather, such as a binder of synthetic leather/artificial leather and surface treatment agents for various leathers. DURANOL™ is used in a wide range of fields such as automobile, furniture, shoes, clothing, and groceries.

Hydrolysis resistance of DURANOL™

It can be seen that PCD polyurethanes are hard to decompose when compared to polyether urethanes and polyester urethanes.

Change in the molecular weight of a polyurethane film immersed in hot water at a temperature of 100°C
Change in the molecular weight of a polyurethane film immersed in hot water at a temperature of 100°C
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[Polyurethane formulation] MDI/Polyol/1,4-BDO=2/1/1

Heat resistance of DURANOL™

PCD polyurethanes show high strength retention even after storage at a high temperature.

Change in the property of a polyurethane film stored at 120°C
Change in the property of a polyurethane film stored at 120°C
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[Polyurethane formulation] H12MDI/Polyol/IPDA=2/1/1

Chemical resistance of DURANOL™

It can be seen that PCD polyurethanes have a smaller swelling rate due to organic solvent when compared to polyether urethanes and polyester urethanes and copolymerized type DURANOL™ has an excellent swelling rate in particular.

Change in the property of a polyurethane film immersed in oleic acid (23°C) for 1 week
Change in the property of a polyurethane film immersed in oleic acid (23°C) for 1 week
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[Polyurethane formulation] MDI/Polyol/1,4-BDO=2/1/1

Flexibility of DURANOL™

Generally, although PCD polyurethane tends to lack flexibility, use of liquid type DURANOL™ allows improvement of flexibility.

Tensile test of polyurethane
Tensile test of polyurethane
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[Measurement condition]
Polyurethane formulation: MDI / Polyol / 1, 4 - BDO = 2 / 1 / 1
Condition: According to JIS K7311
Test piece: 2 mm × 60 mm strip
Measuring instrument: TENSILON tensile testing machine

Abrasion resistance of two-component polyurethane paint using DURANOL™

PCD two-component polyurethane paint offers excellentAbrasion resistance of the paint film.
PCD two-component polyurethane paint offers excellent Abrasion resistance of the paint film.
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[Measurement condition]
Coating formulation : Polyol/DURANATE™[TPA-100]/Solvent/DBTDL
Cured at 80°C×2hr
Taber abrasion test : 500g, 500 times grinding


Compatibility of DURANOL™ and solvents

Liquid type DURANOL™ (T5652•G4672 and G3452) offers excellent handling property and solvent solubility.

  Liquid Solid
solvent/grade T5652 G4672 G3452 T6002 T4692
Toluen 85 85 80 30 8
DMF 85 85 80 20 20
Ethyl acetate 80 80 80 30 10
Acetone 80 80 75 30 20
MEK 90 85 75 40 10
N-octane <1 <1 <1 <1 <1
Methanol <1 <1 <1 <1 <1
Iso-propanol <1 <1 <1 <1 <1

旭化成 アルミペーストAsahi KASEI DURANATE™

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